Homogeneous and supported catalysts for {alpha}-olefin hydrogenation based on complexes of platinum tetrachloride with aliphatic amines

Journal Article · Sat Jul 01 00:00:00 EDT 1995 · Kinetics and Catalysis

OSTI ID:159599

Kliger, E G; Shuikina, L P; Frolov, V M ^[1]

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1. Topchiev Institute of Petrochemical Synthesis, Moscow (Russian Federation)

A new efficient catalyst for a-olefin hydrogenation, a reaction of importance to synthetic fuels preparation, that exhibits the catalytic activity without additional treatment with a reducing agent is obtained by the interaction of PtCl{sub 4} with tri-n-octylamine. Molecular hydrogen and ethanol are found to promote the catalytically active complex. On the basis of the IR spectroscopic investigation, a likely structure of the synthesized complex is proposed. A highly active heterogenized platinum-containing catalyst for the hydrogenation of terminal double bonds is prepared by supporting a homogeneous system on {gamma}-Al{sub 2}O{sub 3}.

• OSTI ID: 159599
• Journal Information: Kinetics and Catalysis, Vol. 36, Issue 4; Other Information: PBD: Jul-Aug 1995; TN: Translated from Kinetika i Kataliz; 36: No. 4, 546-549(1995)
• Country of Publication: United States
• Language: English

Related Subjects

10 SYNTHETIC FUELS
40 CHEMISTRY
PLATINUM CHLORIDES
CATALYTIC EFFECTS
ALKENES
HYDROGENATION
SYNTHETIC FUELS
CHEMICAL PREPARATION
DOUBLE BONDS
ETHANOL
CATALYSTS
AMINES