Thionitrosyl and bridging sulfide complexes of dicarbonyl(hydridotris(3,5-dimethylpyrazolyl)borato)metal (metal = molybdenum and tungsten)
Journal Article
·
· Inorg. Chem.; (United States)
The hydriotris(pyrazolyl)borate, HB(Me/sub 2/PZ)/sub 3//sup -/, has been investigated as an alternative to the cyclopentadienyl system with the idea that the HB(Me/sub 2/PZ)/sub 3//sup -/ ligand might help to inhibit the apparent oxidizing power of N/sub 3/S/sub 3/Cl/sub 3/ and therefore allow the preparation of complexes of the type CpM(CO)/sub 3/NS where Cp = eta/sup 5/-C/sub 5/H/sub 5//sup -/ and M = Mo or W. Detailed preparation schemes and characterization procedures are described for compounds of this type. Both product yields and spectroscopic data for the products are included.
- Research Organization:
- Univ. of Arizona, Tucson
- DOE Contract Number:
- AC02-80ER10746
- OSTI ID:
- 6448961
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 23:17; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Tue Nov 29 23:00:00 EST 1988
· Inorg. Chem.; (United States)
·
OSTI ID:5975272
Syntheses and cadmium-113 NMR studies of five-coordinate complexes with CdN{sub 5}, CdN{sub 3}O{sub 2}, and CdN{sub 3}S{sub 2} central cores. Solid state structures of [HB(3-Phpz){sub 3}]Cd[H{sub 2}B(3,5-Me{sub 2}pz){sub 2}] and [HB(3,5-Me{sub 2}pz){sub 3}]Cd[S{sub 2}CNEt{sub 2}] (pz = Pyrazolyl)
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Wed Sep 27 00:00:00 EDT 1995
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OSTI ID:191950
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OSTI ID:433468
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400302 -- Organic Chemistry-- Isotope Effects-- (-1987)
AZOLES
BARYONS
BORATES
BORON COMPOUNDS
CHEMICAL PREPARATION
COMPLEXES
ELEMENTARY PARTICLES
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
INFRARED SPECTRA
MAGNETIC RESONANCE
MOLYBDENUM COMPLEXES
NITROGEN COMPOUNDS
NUCLEAR MAGNETIC RESONANCE
NUCLEONS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PROTONS
PYRAZOLES
RESONANCE
SPECTRA
SULFUR COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TUNGSTEN COMPLEXES
400201* -- Chemical & Physicochemical Properties
400302 -- Organic Chemistry-- Isotope Effects-- (-1987)
AZOLES
BARYONS
BORATES
BORON COMPOUNDS
CHEMICAL PREPARATION
COMPLEXES
ELEMENTARY PARTICLES
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
INFRARED SPECTRA
MAGNETIC RESONANCE
MOLYBDENUM COMPLEXES
NITROGEN COMPOUNDS
NUCLEAR MAGNETIC RESONANCE
NUCLEONS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PROTONS
PYRAZOLES
RESONANCE
SPECTRA
SULFUR COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
TUNGSTEN COMPLEXES