Palladium(II) acetate catalyzed aromatic substitution reaction
Journal Article
·
· J. Org. Chem.; (United States)
Relative rate measurements indicate that the palladation reaction, although nonselective, adheres to the selectivity relationship for electrophilic aromatic substitution. Kinetic isotope effects and the dependence of the rate on oxidant concentration implicate arylpalladium(II) and arylpalladium(IV) compounds as intermediates in the reactions leading to biaryls and aryl acetates.
- Research Organization:
- Univ. of Chicago, IL
- OSTI ID:
- 6447946
- Journal Information:
- J. Org. Chem.; (United States), Journal Name: J. Org. Chem.; (United States) Vol. 46:8; ISSN JOCEA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400302* -- Organic Chemistry-- Isotope Effects-- (-1987)
ACETATES
AROMATICS
CARBOXYLIC ACID SALTS
DEUTERIUM
HYDROCARBONS
HYDROGEN ISOTOPES
ISOTOPE EFFECTS
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
PALLADIUM COMPOUNDS
STABLE ISOTOPES
TOLUENE
TRANSITION ELEMENT COMPOUNDS
400302* -- Organic Chemistry-- Isotope Effects-- (-1987)
ACETATES
AROMATICS
CARBOXYLIC ACID SALTS
DEUTERIUM
HYDROCARBONS
HYDROGEN ISOTOPES
ISOTOPE EFFECTS
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
PALLADIUM COMPOUNDS
STABLE ISOTOPES
TOLUENE
TRANSITION ELEMENT COMPOUNDS