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Inhibition of mild steel corrosion by sodium dodecyl benzene sulfonate and sodium oleate in acidic solutions

Journal Article · · Corrosion
DOI:https://doi.org/10.5006/1.3287638· OSTI ID:644356
;  [1];  [2]
  1. South Dakota School of Mines and Technology, Rapid City, SD (United States). Dept. of Metallurgical Engineering
  2. Bateman Engineering, Inc., Denver, CO (United States)

Inhibition of mild steel corrosion by sodium dodecyl benzene sulfonate (C{sub 12}H{sub 25}C{sub 6}H{sub 4}SO{sub 3}Na [SDBS]) and sodium oleate (CH{sub 3}[CH{sub 2}]{sub 7}CH{double_bond}CH[CH{sub 2}]{sub 7}COONa) in acidic solutions was investigated using a potentiostat, a lock-in amplifier, a contact angle goniometer, A fourier transform infrared (FTIR) spectrometer, and an ultraviolet (UV)/visible spectrophotometer. In the presence of the organic inhibitors, the corrosion rate was reduced significantly, Anionic SDBS was adsorbed on the positively charged mild steel surface through the electrostatic attraction. However, for sodium oleate, the soluble oleic acid (CH{sub 3}[CH{sub 2}]{sub 7}CH{double_bond}CH[CH]{sub 7}COOH) chemisorbed on the steel surface at the first stage. Then, insoluble colloid adsorbed on the chemisorbed surface through van der Waals forces.

Sponsoring Organization:
USDOE
OSTI ID:
644356
Journal Information:
Corrosion, Journal Name: Corrosion Journal Issue: 8 Vol. 54; ISSN 0010-9312; ISSN CORRAK
Country of Publication:
United States
Language:
English

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