Iron/zeolite catalysts for synthesis of hydrocarbons from CO and H/sub 2/

Journal Article · Thu Jul 10 00:00:00 EDT 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00952836· OSTI ID:6416727

Lapidus, A L; Savel'ev, M M; Muranova, L M; Borisovich, I G; Vasserberg, V E; Minachev, Kh M

Catalysts obtained by deposition of Fe(CO)/sub 5/ on Y zeolites containing bivalent cations are active in the synthesis of C/sub 1/-C/sub 4/ hydrocarbons from CO and H/sub 2/ at 300-400/sup 0/C and atmospheric pressure. The activity of the iron-containing catalysts increases in the same order as the increase in basicity of the cation: BeY < MgY < CaY < SrY < BaY. The content of C/sub 2/-C/sub 3/ olefins in the products from synthesis at 350-373/sup 0/C on the iron-containing zeolites increases in the series BeY < MgY < CaY < SrY < BaY.

• Research Organization: N.D. Zelinskii Institute of Organic Chemistry, Moscow, USSR
• OSTI ID: 6416727
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:1; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical &amp; Physicochemical Properties
ALKALINE EARTH METAL COMPOUNDS
ALKANES
ALKENES
BARIUM COMPOUNDS
BERYLLIUM COMPOUNDS
CALCIUM COMPOUNDS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONYLS
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CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHROMATOGRAPHY
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ELEMENTS
ETHANE
ETHYLENE
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROGEN
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
IRON COMPOUNDS
MAGNESIUM COMPOUNDS
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METHANE
MINERALS
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PROPANE
SEPARATION PROCESSES
STRONTIUM COMPOUNDS
TEMPERATURE DEPENDENCE
TRANSITION ELEMENT COMPOUNDS
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