Catalytic properties of iron carbonyls supported on zeolites in hydrocarbon synthesis from CO and H/sub 2/

Journal Article · Mon Jul 01 00:00:00 EDT 1985 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF01157320· OSTI ID:5541513

Lapidus, A L; Kondrat'ev, L T; Muranova, L M; Savel'ev, M M; Sominskii, S D

The authors report on an investigation of Fe(CO)/sub 5//NaY and Fe(CO)/sub 3//CaY catalyts in the synthesis of hydrocarbons from CO and H/sub 2/, and also on an IR spectroscopic study of the catalysts under the conditions of synthesis. It has been shown that catalysts obtained on the basis of iron pentacarbonyl and Nay or CaY zeolite are active in the synthesis of alkanes from carbon monoxide and hydrogen. IR spectroscopy has shown that when Fe(CO)/sub 5/ is adsorbed on NaY or CaY zeolite, the complexes (Fe/sub 3/(CO)/sub 11/)/sup 2 -/, (Fe/sub 4/(CO)/sub 13/)/sup 2 -/, and (HFe/sub 3/(CO)/sub 11/)are formed, and the active centers of the catalyst are formed from these complexes under the conditions of synthesis.

• Research Organization: N.D. Zelinskii Institute of Organic Chemistry, Acadeny of Sciences of the USSR
• OSTI ID: 5541513
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:1, PT. 1; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

090121* -- Hydrocarbon Fuels-- Chemical Synthesis-- (1976-1989)
10 SYNTHETIC FUELS
ADSORPTION
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONYLS
CATALYST SUPPORTS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
ELEMENTS
HEAT TREATMENTS
HYDROCARBONS
HYDROGEN
INFRARED SPECTRA
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
IRON COMPOUNDS
MATERIALS
MINERALS
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
SORPTION
SPECTRA
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
ZEOLITES