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Pulse radiolysis study of the reactivity of neptunoyl ions relative to inorganic free radicals (in Russian)

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
DOI:https://doi.org/10.1007/BF00952941· OSTI ID:6415971
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Pulse radiolysis was used to find the rate constants for the reactions of OH, HSO/sub 4/, NO/sub 3/, and Cl/sub 2/ radicals with neptunoyl ions. Change in the NO/sub 3//sup -/ and H/sup +/ ion concentrations do not affect the term k(NO/sub 3/ + NpO/sub 2//sup +/), while k(Cl/sub 2//sup -/ + NpO/sub 2//sup +/ increases with increasing chloride concentration due to the formation of neptunoyl ion chlorocomplexes.

Research Organization:
Institute of Physical Chemistry, Moscow, USSR
OSTI ID:
6415971
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:2; ISSN BACCA
Country of Publication:
United States
Language:
Russian

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400600* -- Radiation Chemistry
ABSORPTIVITY
ACTINIDE COMPOUNDS
ACTIVATION ENERGY
ALKALI METAL COMPOUNDS
ALKALINE EARTH METAL COMPOUNDS
ANIONS
ANTITHYROID DRUGS
BROMINE COMPOUNDS
CARBONIC ACID DERIVATIVES
CATIONS
CHARGED PARTICLES
CHEMICAL RADIATION EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
DECOMPOSITION
DRUGS
ENERGY
HALIDES
HALOGEN COMPOUNDS
HORMONE ANTAGONISTS
HYDROCHLORIC ACID
HYDROGEN COMPOUNDS
HYDROXIDES
INORGANIC ACIDS
IONS
KINETICS
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
LITHIUM NITRATES
LITHIUM PERCHLORATES
MAGNESIUM CHLORIDES
MAGNESIUM COMPOUNDS
NEPTUNIUM COMPOUNDS
NITRATES
NITRIC ACID
NITROGEN COMPOUNDS
OPTICAL PROPERTIES
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXIDATION
OXYGEN COMPOUNDS
PERCHLORATES
PERCHLORIC ACID
PHYSICAL PROPERTIES
PULSE TECHNIQUES
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIOLYSIS
REACTION KINETICS
REDOX POTENTIAL
REDUCTION
SPECTROPHOTOMETRY
SULFURIC ACID
THIOCYANATES
TRANSURANIUM COMPOUNDS