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U.S. Department of Energy
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Ethanol from cellulosics

Journal Article · · Chem. Eng. Prog.; (United States)
OSTI ID:6399097

The current major research and development effort in the U.S. to improve technology for the conversion of cellulosic waste is justified by the potential utilization of hundreds of millions of tons per year of agricultural and forest wastes. Cellulose must first be hydrolyzed to hexose monosacharides (mainly glucose) before it can be fermented to ethanol. Although many hydrolysis processes have been investigated, only hydrolysis using dilute mineral acid has been commercialized. In the reported experiments, an ethanol-from-cellulose process simulation was developed for implementation on an IBM 5120 computer, utilizing APL computer language. The model calculates material balances, utility balances and factored capital costs for the entire process, starting with any cellulosic feedstock and producing anhydrous ethanol and other by-products. Data are presented which demonstrate that prehydrolysis is the most useful pretreatment. It can accomplish virtually the same physical changes as steam explosion, while also performing a mild hydrolysis on accessible cellulose. Yields are higher with this step than without, and formation of by-product HMF and furfural is minimized.

Research Organization:
Chem Syst Inc, Tarrytown, NY, USA
OSTI ID:
6399097
Journal Information:
Chem. Eng. Prog.; (United States), Journal Name: Chem. Eng. Prog.; (United States) Vol. 78:8; ISSN CEPRA
Country of Publication:
United States
Language:
English