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Radical-anions of aromatic compounds. X. Radical-anions of polychlorinated derivatives of nitrobenzene (in Russian)

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6388458

The radical-anions of polychlorinated derivatives of nitrobenzene were generated by the electrochemical reduction of nitrobenzene derivatives containing 2-5 chlorine atoms in DMFA and in its mixtures with water. The dependence of the hfc constants on the number of position of the chlorine atoms and on the water content of the binary mixture of solvents is analyzed in terms of ideas about the electronic and steric effects of the chlorine atoms and the association of the radical-anions with the water molecules.

Research Organization:
Novosibirsk Institute of Organic Chemistry, USSR
OSTI ID:
6388458
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 22:6; ISSN JOCYA
Country of Publication:
United States
Language:
Russian

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