Kinetic isotope effect in the free-radical isomerization and fragmentation of acetals
Journal Article
·
· Dokl. Chem. (Engl. Transl.); (United States)
OSTI ID:6388103
This work studied the kinetics of homolytic liquid-phase conversions of 1,3-dioxolane, 2,2-dideuterium-1,3-dioxolane, 3-butyl-1,3-oxazolidine, and 2,2-dideuterium-3-butyl-1,3-oxazolidine, dipropoxymethane, and dideuterodipropoxymethane, initiated by the thermal decomposition of tert-butyl peroxide.
- Research Organization:
- Ufa Petroleum Inst., USSR
- OSTI ID:
- 6388103
- Journal Information:
- Dokl. Chem. (Engl. Transl.); (United States), Journal Name: Dokl. Chem. (Engl. Transl.); (United States) Vol. 262:4-6; ISSN DKCHA
- Country of Publication:
- United States
- Language:
- English
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Free-radical reactions of 2-ethoxy-1,3-oxathiolane
Isotope effect in homolytic liquid-phase fragmentation of diethoxymethane
THE PRODUCTION AND DETECTION OF FREE RADICALS BY CHEMICAL AND SPECTROGRAPHIC METHODS. Final Report, October 29, 1960-OCTOBER 28, 1962
Journal Article
·
Tue Dec 31 23:00:00 EST 1985
· Chem. Heterocycl. Compd. (Engl. Transl.); (United States)
·
OSTI ID:6962335
Isotope effect in homolytic liquid-phase fragmentation of diethoxymethane
Journal Article
·
Tue Jan 31 23:00:00 EST 1984
· Dokl. Chem. (Engl. Transl.); (United States)
·
OSTI ID:5880452
THE PRODUCTION AND DETECTION OF FREE RADICALS BY CHEMICAL AND SPECTROGRAPHIC METHODS. Final Report, October 29, 1960-OCTOBER 28, 1962
Technical Report
·
Fri Oct 30 23:00:00 EST 1964
·
OSTI ID:4169948
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
400302* -- Organic Chemistry-- Isotope Effects-- (-1987)
ACETALS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DECOMPOSITION
DEUTERIUM
ETHERS
HYDROGEN ISOTOPES
ISOMERIZATION
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LIGHT NUCLEI
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
REACTION KINETICS
STABLE ISOTOPES
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
400302* -- Organic Chemistry-- Isotope Effects-- (-1987)
ACETALS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DECOMPOSITION
DEUTERIUM
ETHERS
HYDROGEN ISOTOPES
ISOMERIZATION
ISOTOPE EFFECTS
ISOTOPES
KINETICS
LIGHT NUCLEI
NUCLEI
ODD-ODD NUCLEI
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
REACTION KINETICS
STABLE ISOTOPES