THE PRODUCTION AND DETECTION OF FREE RADICALS BY CHEMICAL AND SPECTROGRAPHIC METHODS. Final Report, October 29, 1960-OCTOBER 28, 1962
Technical Report
·
OSTI ID:4169948
Compounds with structures similar to those present in proteins were brought into reaction with radical-producing reagents to form intermediate free radicals. The structures and behavior of these intermediate free radicals were studied. The existence of a sulfonium radical intermediate was investigated and evidence to support the formation of this radical, as a transient intermediate in some free radical reactions with phenyl sulfide, was found. The thermal decomposition of tert-butyl peroxide in the presence of N-methyl pyrrole gave two isomeric products. Study of the tert-butyl peroxide-initiated free radical reactions of cyclohexane oxide and propylene sulfide resulted in the discovery of a type of radical abstraction and rearrangement not previously described. Thermal-decomposition products of peroxyesters were studied for identification of free radicals. One hundred and twenty-eight references are included. (M.C.G.)
- Research Organization:
- Connecticut. Univ., Storrs
- NSA Number:
- NSA-18-000254
- OSTI ID:
- 4169948
- Report Number(s):
- AD-299008
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ALKANES
AROMATICS
ATOMS
BIBLIOGRAPHY
BUTYL RADICALS
CARBON 10
CHEMICAL REACTIONS
CHEMISTRY
COMPOUNDS
CYCLOALKANES
DECONTAMINATION
EFFICIENCY
ESTERS
FREE RADICALS
GAMMA RADIATION
HEPTANE
HEXANE
HYDROCARBONS
HYDROGEN
IRRADIATION
ISOMERS
LATTICES
LIQUIDS
LOW TEMPERATURE
METHANE
METHYL RADICALS
MOLECULES
NUCLEAR REACTIONS
OCTANE
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PEROXIDES
PETROCHEMISTRY
PETROLEUM
PHENYL RADICALS
PREPARATION
PRODUCTION
PROPYLENE
PYRROLES
QUALITATIVE ANALYSIS
QUANTITY RATIO
RADIATION CHEMISTRY
RADIATION DOSES
REACTION KINETICS
ROCKS
SULFIDES
THERMODYNAMICS
AROMATICS
ATOMS
BIBLIOGRAPHY
BUTYL RADICALS
CARBON 10
CHEMICAL REACTIONS
CHEMISTRY
COMPOUNDS
CYCLOALKANES
DECONTAMINATION
EFFICIENCY
ESTERS
FREE RADICALS
GAMMA RADIATION
HEPTANE
HEXANE
HYDROCARBONS
HYDROGEN
IRRADIATION
ISOMERS
LATTICES
LIQUIDS
LOW TEMPERATURE
METHANE
METHYL RADICALS
MOLECULES
NUCLEAR REACTIONS
OCTANE
ORGANIC OXYGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PEROXIDES
PETROCHEMISTRY
PETROLEUM
PHENYL RADICALS
PREPARATION
PRODUCTION
PROPYLENE
PYRROLES
QUALITATIVE ANALYSIS
QUANTITY RATIO
RADIATION CHEMISTRY
RADIATION DOSES
REACTION KINETICS
ROCKS
SULFIDES
THERMODYNAMICS