First example of an organogallium compound containing a gallium-tellurium bond: Synthesis, properties, and molecular structure of ((Me sub 3 CCH sub 2 ) sub 2 GaTePh) sub 2
- State Univ. of New York, Buffalo (USA)
- Eastman Kodak Co., Rochester, NY (USA)
The first example of an organogallium compound with a Ga-Te bond, ((Me{sub 3}CCH{sub 2}){sub 2}GaTePh){sub 2}, which is stable at room temperature, has been synthesized and characterized by elemental analyses, IR, {sup 1}H NMR, and {sup 125}Te NMR spectroscopies, and an X-ray structural study. The dimeric molecule crystallizes in the monoclinic space group P2{sub 1}/c with unit cell dimensions of a = 18.864 (7) {angstrom}, b = 10.041 (5) {angstrom}, c = 19.869 (9) {angstrom}, {beta} = 101.80 (3){degree}, V = 3,684 (5) {angstrom}{sup 3}, Z = 4, D{sub calcd} = 1.505 g cm{sup {minus}3}, R = 0.030, and R{sub w} = 0.035.
- OSTI ID:
- 6378797
- Journal Information:
- Organometallics; (USA), Journal Name: Organometallics; (USA) Vol. 9:6; ISSN 0276-7333; ISSN ORGND
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
DATA
DATA ANALYSIS
EXPERIMENTAL DATA
GALLIUM COMPOUNDS
INFORMATION
MEASURING INSTRUMENTS
MEASURING METHODS
MOLECULAR STRUCTURE
NUMERICAL DATA
PHYSICAL PROPERTIES
SYNTHESIS
TELLURIUM COMPOUNDS
400201* -- Chemical & Physicochemical Properties
DATA
DATA ANALYSIS
EXPERIMENTAL DATA
GALLIUM COMPOUNDS
INFORMATION
MEASURING INSTRUMENTS
MEASURING METHODS
MOLECULAR STRUCTURE
NUMERICAL DATA
PHYSICAL PROPERTIES
SYNTHESIS
TELLURIUM COMPOUNDS