Compounds of thiourea and its complexes with metal salts

Journal Article · Fri Aug 01 04:00:00 EDT 1986 · Sov. J. Coordinat. Chem.; (United States)

OSTI ID:6366127

Vorob'ev-Desyatovskii, N V; Kukushkin, Yu N; Sibirskaya, V V

A review of the literature devoted to compounds of thiourea has been given. Three types of compounds have been described: clathrates, ionic complexes, and coordination compounds. Attention has been focused on the thiourea complexes of transition metals. The results of investigations of the structure of these complexes with the aid of x-ray diffraction analysis and other physicochemical methods have been considered. The stability and lability of the coordination compounds of thiourea and its N- and N,N'-substituted derivatives, as well as the features of these ligands in substitution reactions, have been characterized. The acid-base, redox, and thermal properties of thioamide complexes have been discussed.

• Research Organization: Lensovet Leningrad Technological Institute, USSR
• OSTI ID: 6366127
• Journal Information: Sov. J. Coordinat. Chem.; (United States), Journal Name: Sov. J. Coordinat. Chem.; (United States) Vol. 11:10; ISSN SJCCD
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360602 -- Other Materials-- Structure & Phase Studies
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
BINDING ENERGY
BOND ANGLE
BOND LENGTHS
BROMIDES
BROMINE COMPOUNDS
CARBONIC ACID DERIVATIVES
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHLORIDES
CHLORINE COMPOUNDS
CLATHRATES
COHERENT SCATTERING
COMPLEXES
COMPLEXOMETRY
COORDINATION NUMBER
COORDINATION VALENCES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
CRYSTALS
DEPOSITION
DIFFRACTION
DIMENSIONS
DOCUMENT TYPES
ELECTRONIC STRUCTURE
ELECTRONS
ELEMENTARY PARTICLES
ENERGY
FERMIONS
GAMMA SPECTRA
HALIDES
HALOGEN COMPOUNDS
IODIDES
IODINE COMPOUNDS
IONIC CRYSTALS
KINETICS
LATTICE VIBRATIONS
LENGTH
LEPTONS
LIGANDS
MOESSBAUER EFFECT
MOLECULAR STRUCTURE
ORGANIC COMPOUNDS
ORGANIC SULFUR COMPOUNDS
REACTION KINETICS
REDOX POTENTIAL
REVIEWS
SCATTERING
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
SURFACE COATING
THIOUREAS
TRANSITION ELEMENT COMPLEXES
USES
VALENCE
X-RAY DIFFRACTION