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U.S. Department of Energy
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Photovoltaic devices using a-Si:H from higher order silanes. Semiannual report, 1 September 1983-29 February 1984

Technical Report ·
OSTI ID:6358629

This report summarizes research performed during a six-month period on hydrogenated amorphous silicon, prepared by chemical vapor deposition using flow methods rather than a static method in order to deposit from a time-invariant gas phase chemistry. Both low-pressure and atmospheric-pressure systems were employed. The feedstock gases were electronic-grade higher order silanes (principally disilane) manufactured by silent electric discharge. Because of the historically poor performance of CVD p layers in p-i-n devices, an effort was made to develop a higher quality p layer. Both silane/diborane and disilane/diborane mixtures were investigated. Using disilane/diborane mixtures at low pressures and very low temperatures (200/sup 0/C) significantly improved LPCVD p layers. P-i-n devices employing these p layers exhibited open-circuit voltages up to 723 mV.

Research Organization:
Chronar Corp., Princeton, NJ (USA)
DOE Contract Number:
AC02-83CH10093
OSTI ID:
6358629
Report Number(s):
SERI/STR-211-2498; ON: DE85000522
Country of Publication:
United States
Language:
English