Asymmetric nitrogen. Communication 49. Interaction of the unshared electron pairs of the nitrogen atoms in bicyclic diaziridines
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:6358285
According to data from model nonempirical calculations and photoelectronic spectroscopy, the interaction of cis- and trans-oriented unshared electron pairs of N atoms in diaziridines may change substantially as a function of the degree of pyramidal character of these atoms; in particular, this is observed in bicyclic diaziridines with a change in the size or conformation of the ring fused with the diaziridine ring. A method for the synthesis of bicyclic diaziridines, viz., 1,n-diazabicyclo(m.1.0)-alkanes (n = 6, 7; m = 3, 4), under interphase-catalysis conditions was developed.
- Research Organization:
- Institute of Chemical Physics, Moscow, USSR
- OSTI ID:
- 6358285
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:8; ISSN BACCA
- Country of Publication:
- United States
- Language:
- English
Similar Records
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ADDUCTS
ALKANES
ATOMIC MODELS
AZINES
BINDING ENERGY
BOND ANGLE
CATALYSIS
CHEMICAL BONDS
CONFIGURATION INTERACTION
CONFORMATIONAL CHANGES
CYCLOALKANES
CYCLOHEXANE
ELECTRON SPECTROSCOPY
ELECTRONIC STRUCTURE
ELECTRONS
ELEMENTARY PARTICLES
ELEMENTS
ENERGY
ENERGY LEVELS
FERMIONS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYPERFINE STRUCTURE
IONIZATION POTENTIAL
LEPTONS
MATHEMATICAL MODELS
MOLECULAR MODELS
MOLECULAR ORBITAL METHOD
MOLECULAR STRUCTURE
NITROGEN
NMR SPECTRA
NONMETALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
PYRIDINES
SPECTRA
SPECTROSCOPY
SYNTHESIS
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ADDUCTS
ALKANES
ATOMIC MODELS
AZINES
BINDING ENERGY
BOND ANGLE
CATALYSIS
CHEMICAL BONDS
CONFIGURATION INTERACTION
CONFORMATIONAL CHANGES
CYCLOALKANES
CYCLOHEXANE
ELECTRON SPECTROSCOPY
ELECTRONIC STRUCTURE
ELECTRONS
ELEMENTARY PARTICLES
ELEMENTS
ENERGY
ENERGY LEVELS
FERMIONS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYPERFINE STRUCTURE
IONIZATION POTENTIAL
LEPTONS
MATHEMATICAL MODELS
MOLECULAR MODELS
MOLECULAR ORBITAL METHOD
MOLECULAR STRUCTURE
NITROGEN
NMR SPECTRA
NONMETALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
PYRIDINES
SPECTRA
SPECTROSCOPY
SYNTHESIS