Reaction of ethyl diazoacetate with N-2,7-octadienylanilines catalyzed by compounds of copper
The reaction of EDA with N-2,7-octadienyl derivatives of aniline, catalyzed by the complex copper bis(N-(R,S)-..cap alpha..-phenylethylsalicylaldiminate), was studied. The reaction of N-2,7-octadienylanilines, and also of bis(N-2,7-octadienyl)- and N-acetyle-N-2-7-octadienylanilines, with EDA proceeds with the formation of the products of the cyclopropanation at the terminal vinyl group or the disubstituted double bond. In the case of the N-alkyl-N-2,7-octadienyl anilines, the skeletal isomerization of the octadienyl anilines, the skeletal isomerization of the octadienyl radical in the initial amine with the simultaneous introduction of ethoxycarbonylcarbene at the allylic C-H bond takes place.
- Research Organization:
- Institute of Chemistry, Ufa, USSR
- OSTI ID:
- 6357248
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:12; ISSN BACCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
400201* -- Chemical & Physicochemical Properties
ACETATES
ALKANES
AMINES
ANILINE
AROMATICS
CARBON 13
CARBON ISOTOPES
CARBOXYLIC ACID SALTS
CATALYSIS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHEMICAL SHIFT
COMPLEXES
COPPER COMPLEXES
CYCLOALKANES
DIAZO COMPOUNDS
ELECTRON SPIN RESONANCE
EVEN-ODD NUCLEI
HYDROCARBONS
INFRARED SPECTRA
ISOMERIZATION
ISOTOPES
LIGHT NUCLEI
MAGNETIC RESONANCE
MASS SPECTRA
MULTIPLETS
NMR SPECTRA
NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PROPANE
RESONANCE
SPECTRA
STABLE ISOTOPES
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
TOLUIDINES
TRANSITION ELEMENT COMPLEXES
YIELDS