Addition of diethyl bromomalonate and diethyl dibromomalonate to vinyltrimethylsilane

Journal Article · Sun Apr 20 04:00:00 EST 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:6357115

Amriev, R A; Vinogradova, L V; Velichko, F K

Diethyl dibromomalonate and diethyl bromomalonate add to vinyltrimethylsilane upon initiation by dibenzoyl peroxide to form the diethyl esters of (2-bromo-2-trimethylsilylethyl)-bromomalonic acid and (2-bromo-2-trimethylsilylethyl)malonic acid, respectively. The reactivity of diethyl dibromomalonate in this addition reaction is higher than for diethyl bromomalonate. Metal carbonyl initiation in this reaction is not very efficient. In the case of diethyl bromomalonate, reduction of the addend becomes the major reaction in the case of such initiation.

• Research Organization: A.N. Nesmeyanov Institute of Heteroorganic Compounds, Moscow, USSR
• OSTI ID: 6357115
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:10; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACTIVATION ENERGY
CARBONYLS
CARBOXYLIC ACID ESTERS
CARBOXYLIC ACIDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHROMATOGRAPHY
COMPARATIVE EVALUATIONS
DICARBOXYLIC ACIDS
ENERGY
ESTERS
HOMOGENEOUS CATALYSIS
HYDRIDES
HYDROGEN COMPOUNDS
IRON COMPOUNDS
KINETICS
MALONIC ACID
MANGANESE COMPOUNDS
NMR SPECTRA
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC SILICON COMPOUNDS
OXYGEN COMPOUNDS
PEROXIDES
REACTION KINETICS
SEPARATION PROCESSES
SILANES
SILICON COMPOUNDS
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
TRANSITION ELEMENT COMPOUNDS