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Disruption of the chemiluminescence autooscillations of the belousov-zhabotinskii reaction as a result of deuteration of the solvent

Journal Article · · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
DOI:https://doi.org/10.1007/BF00948084· OSTI ID:7150858
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This paper shows that deuteration significantly decreases the rate of enolization of malonic acid and, thus, the rate of the bromination of the malonic acid to form bromomalonic acid. As a result, the concentration of bromomalonic acid in the D/sub 2/O system does not reach the critical value required for the generation of oscillations.
Research Organization:
Institute of Chemistry, Acad. of Sci., Ufa
OSTI ID:
7150858
Journal Information:
Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 34:4,PT.2; ISSN BACCA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALCOHOLS
ALKALI METAL COMPOUNDS
AMINES
ANTI-INFECTIVE AGENTS
ANTIMICROBIAL AGENTS
AZINES
BROMATES
BROMINATION
BROMINE COMPOUNDS
CARBOXYLIC ACIDS
CHEMICAL REACTIONS
CHEMILUMINESCENCE
CHEMISTRY
CHLORIDES
CHLORINE COMPOUNDS
DEUTERATION
DEUTERIUM COMPOUNDS
DICARBOXYLIC ACIDS
DRUGS
ELEMENTS
ENOLS
HALIDES
HALOGEN COMPOUNDS
HALOGENATION
HEAVY WATER
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
HYDROXY COMPOUNDS
INORGANIC ACIDS
LUMINESCENCE
MALONIC ACID
METALS
METHYLENE BLUE
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
OXYGEN COMPOUNDS
PHENOTHIAZINES
PHOTOCHEMISTRY
PLATINUM METALS
POTASSIUM COMPOUNDS
RUTHENIUM
SULFURIC ACID
TRANSITION ELEMENTS
WATER