Alkali-metal intercalates of layered yttrium chloride oxide and their hydration reactions
Journal Article
·
· Inorg. Chem.; (United States)
Reactions of M Cl, M = Li-Cs, with Y and YCl3-Y2O3 or YOCl at 950C resulted in high yields of layered M/sub x/ YClO with three types of structures. These structures have been identified with the aid of Guinier powder photographs, and the structure of two types have been established by a single-crystal x-ray study of one member of each. Crystal parameters of the intercalates are presented. Diffraction powder patterns of samples exposed to air indicated that the samples hydrated with little or no oxidation.
- Research Organization:
- Iowa State Univ., Ames
- DOE Contract Number:
- W-7405-ENG-82
- OSTI ID:
- 6344914
- Journal Information:
- Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 24:24; ISSN INOCA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKALI METAL COMPOUNDS
CESIUM COMPOUNDS
CHEMICAL PREPARATION
CHLORIDES
CHLORINE COMPOUNDS
CLATHRATES
COHERENT SCATTERING
CRYSTAL STRUCTURE
DATA
DIFFRACTION
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
INFORMATION
LITHIUM COMPOUNDS
NUMERICAL DATA
OXYCHLORIDES
OXYGEN COMPOUNDS
SCATTERING
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
X-RAY DIFFRACTION
YTTRIUM CHLORIDES
YTTRIUM COMPOUNDS
400201* -- Chemical & Physicochemical Properties
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ALKALI METAL COMPOUNDS
CESIUM COMPOUNDS
CHEMICAL PREPARATION
CHLORIDES
CHLORINE COMPOUNDS
CLATHRATES
COHERENT SCATTERING
CRYSTAL STRUCTURE
DATA
DIFFRACTION
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
INFORMATION
LITHIUM COMPOUNDS
NUMERICAL DATA
OXYCHLORIDES
OXYGEN COMPOUNDS
SCATTERING
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
X-RAY DIFFRACTION
YTTRIUM CHLORIDES
YTTRIUM COMPOUNDS