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Interstitial and intercalation chemistry of the double-metal-layered yttrium monochloride

Journal Article · · Inorg. Chem.; (United States)
DOI:https://doi.org/10.1021/ic00162a004· OSTI ID:5581144
; ;

The incorporation of guest impurity atoms is demonstrated in the chemistry of yttrium chloride(YCl). These new phases are all synthesized as black plates by stoichiometric reaction of metal powder or strips with the trichloride and M/sup I/Cl(M/sup I/ = lithium-cesium (LiCs)), chloride yttrium oxide (Y/sub 2/O/sub 3/), scandium chloride (ScCl), yttrium oxychloride (YOCl), or carbon (C) within sealed tantalum tubing at 950/sup 0/C for 1 to 3 weeks. The new phases are Li/sub 0/ /sub 09/YCl, ScClC/sub 0/ /sub 5/, M/sub 0/ /sub 1//sup I/YClO, and M/sub 0/ /sub 2//sup I/YClC/sub 0/ /sub 5/. The yields for all the compounds except Li/sub 0/ /sub 09/YCl are greater than 90%. The products are stable at high temperatures and well crystallized, in contrast to many reported intercalation compounds. The structure refinement is discussed. 1 figure.

Research Organization:
Ames Lab., IA
DOE Contract Number:
W-7405-ENG-82
OSTI ID:
5581144
Journal Information:
Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 22:20; ISSN INOCA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
ALLOYS
CARBIDES
CARBON
CARBON COMPOUNDS
CESIUM CARBIDES
CESIUM CHLORIDES
CESIUM COMPOUNDS
CHALCOGENIDES
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COHERENT SCATTERING
CRYSTAL DEFECTS
CRYSTAL STRUCTURE
DATA
DIFFRACTION
ELEMENTS
EXPERIMENTAL DATA
HALIDES
HALOGEN COMPOUNDS
INFORMATION
INTERMETALLIC COMPOUNDS
INTERSTITIALS
LITHIUM CARBIDES
LITHIUM CHLORIDES
LITHIUM COMPOUNDS
LITHIUM HALIDES
MEDIUM TEMPERATURE
NONMETALS
NUMERICAL DATA
OXIDES
OXYCHLORIDES
OXYGEN COMPOUNDS
POINT DEFECTS
SCANDIUM CARBIDES
SCANDIUM CHLORIDES
SCANDIUM COMPOUNDS
SCATTERING
STOICHIOMETRY
STRUCTURAL CHEMICAL ANALYSIS
TEMPERATURE DEPENDENCE
TIME DEPENDENCE
TRANSITION ELEMENT COMPOUNDS
VERY HIGH TEMPERATURE
X-RAY DIFFRACTION
YIELDS
YTTRIUM CARBIDES
YTTRIUM CHLORIDES
YTTRIUM COMPOUNDS
YTTRIUM OXIDES