Carbon monoxide activation by organoactinides. Catalytic hydrogenation of inserted CO

Journal Article · Wed Jun 17 04:00:00 EDT 1981 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00402a056· OSTI ID:6341852

Maatta, E A; Marks, T J

This paper reports that homogeneous hydrogenation of the eta/sup 2/-acyls to the corresponding alkoxide derivatives (M(eta/sup 2/-COR) ..-->.. M-OCH/sub 2/R) can be readily effected at room temperature and less than 1 atm of H/sub 2/ pressure by using the hydride (Th((CH/sub 3/)/sub 5/C/sub 5/)/sub 2/H/sub 2/)/sub 2/ as a catalyst (M = Th or U).

• Research Organization: Northwestern Univ., Evanston, IL
• OSTI ID: 6341852
• Journal Information: J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 103:12; ISSN JACSA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
400702 -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ACTINIDE COMPLEXES
CATALYTIC EFFECTS
CHEMICAL REACTIONS
COMPLEXES
HETEROCYCLIC OXYGEN COMPOUNDS
HYDROGENATION
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
THORIUM COMPLEXES
URANIUM COMPLEXES