Carbon monoxide activation by organoactinides. Migratory CO insertion into metal-hydrogen bonds to produce mononuclear formyls
Journal Article
·
· J. Am. Chem. Soc.; (United States)
Spontaneous and rapid insertion of CO into certain organoactinide hydrides is reported. The sterically unencumbered bis(pentamethylcyclopentadienyl) 5f hydrides such as (Th((CH/sub 3/)/sub 5/C/sub 5/)/sub 2/(..mu..-H)H)/sub 2/ react rapidly with excess CO at -78/sup 0/C. The carbonylation of alkoxy hydroxides is also described. Thermodynamic and kinetic aspects of the reactions are reported. (BLM)
- Research Organization:
- Northwestern Univ., Evanston, IL
- OSTI ID:
- 5547905
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 103:23; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Carbon monoxide activation by organoactinides: a comparative synthetic, thermodynamic, kinetic, and mechanistic investigation of migratory CO insertion into actinide-carbon and actinide-hydrogen bonds to yield eta/sup 2/-acyls and eta/sup 2/-formyls
Synthesis and chemistry of pentamethylcyclopentadienyl complexes of thorium and uranium: the new chapter in organoactinide chemistry
Organoactinide carbonylation and carboxylation chemistry. Structural, electronic, bond energy, and photochemical effects on migratory insertion in the tris(cyclopentadienyl)thorium hydrocarbyl series
Journal Article
·
Tue Nov 13 23:00:00 EST 1984
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5959965
Synthesis and chemistry of pentamethylcyclopentadienyl complexes of thorium and uranium: the new chapter in organoactinide chemistry
Thesis/Dissertation
·
Wed Dec 31 23:00:00 EST 1980
·
OSTI ID:5313736
Organoactinide carbonylation and carboxylation chemistry. Structural, electronic, bond energy, and photochemical effects on migratory insertion in the tris(cyclopentadienyl)thorium hydrocarbyl series
Journal Article
·
Wed Jun 13 00:00:00 EDT 1984
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6454103
Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ACTINIDE COMPOUNDS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
DATA
EXPERIMENTAL DATA
INFORMATION
KINETICS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS
400702* -- Radiochemistry & Nuclear Chemistry-- Properties of Radioactive Materials
ACTINIDE COMPOUNDS
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
DATA
EXPERIMENTAL DATA
INFORMATION
KINETICS
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
REACTION KINETICS