Kinetics and mechanism of reactions of substituted. cap alpha. -oxides with carboxylic acids. VIII. Reactions of n-glycidylamines with carboxylic acids
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6334040
The kinetics and thermodynamics of the reaction of a series of N-glycidylamines with carboxylic acids in an aprotic solvent, chlorobenzene, were studied. The character of the influence of the donor-acceptor substituents in the structure of glycidylamines on the rate of the reactions studied was revealed. The structure of the reaction products was studied by PMR spectroscopy. The data obtained confirmed the mechanism of generally basic intramolecular catalysis already proposed for the reactions of N-glycidylamines with carboxylic acids.
- OSTI ID:
- 6334040
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Journal Name: Kinet. Catal. (Engl. Transl.); (United States) Vol. 28:6; ISSN KICAA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETIC ACID
AMINES
AROMATICS
BENZOIC ACID
CARBOXYLIC ACIDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED AROMATIC HYDROCARBONS
EQUATIONS
HALOGENATED AROMATIC HYDROCARBONS
HOMOGENEOUS CATALYSIS
ISOMERIZATION
KINETIC EQUATIONS
KINETICS
MONOCARBOXYLIC ACIDS
NMR SPECTRA
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
REACTION KINETICS
SOLVENT PROPERTIES
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS
400201* -- Chemical & Physicochemical Properties
ACETIC ACID
AMINES
AROMATICS
BENZOIC ACID
CARBOXYLIC ACIDS
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED AROMATIC HYDROCARBONS
EQUATIONS
HALOGENATED AROMATIC HYDROCARBONS
HOMOGENEOUS CATALYSIS
ISOMERIZATION
KINETIC EQUATIONS
KINETICS
MONOCARBOXYLIC ACIDS
NMR SPECTRA
ORGANIC ACIDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
REACTION KINETICS
SOLVENT PROPERTIES
SPECTRA
STRUCTURAL CHEMICAL ANALYSIS