Reaction intermediates on Fe/TiO/sub 2/ during CO/H/sub 2/ reaction
Journal Article
·
· J. Catal.; (United States)
OSTI ID:6321486
The nature of the surface species present on 10% Fe/TiO/sub 2/ in the low-temperature reduced state (558 K) has been studied after short times of reaction in 10% CO/H/sub 2/ at 558 K and 1 atm. After various reaction times the surface has been titrated by H/sub 2/, O/sub 2/, or D/sub 2/. The results show that the surface during reaction is covered with about 46 ..mu..mol/g of CH and large quantities of surface carbidic carbon. The intermediate for the reaction of 10% C/sub 2/H/sub 4//H/sub 2/ appears to be only CH. 7 references, 5 figures, 4 tables.
- Research Organization:
- Univ. of Connecticut, Storrs
- OSTI ID:
- 6321486
- Journal Information:
- J. Catal.; (United States), Journal Name: J. Catal.; (United States) Vol. 89:2; ISSN JCTLA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Kinetic and Moessbauer study of the CO/H/sub 2/ reaction over Fe/TiO/sub 2/ reduced at various temperatures
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Ultrasonic measurements of the vibrational relaxation of UF/sub 6/: Mixtures with H/sub 2/, CH/sub 4/, and C/sub 2/H/sub 6/
Journal Article
·
Mon Oct 01 00:00:00 EDT 1984
· J. Catal.; (United States)
·
OSTI ID:6458676
Transient kinetic study of the reaction of CH[sub 4] and C[sub 2]H[sub 6] with the lattice oxygen of Li[sup +]-doped TiO[sub 2] catalyst
Journal Article
·
Tue Jun 01 00:00:00 EDT 1993
· Journal of Catalysis; (United States)
·
OSTI ID:6154098
Ultrasonic measurements of the vibrational relaxation of UF/sub 6/: Mixtures with H/sub 2/, CH/sub 4/, and C/sub 2/H/sub 6/
Journal Article
·
Mon Oct 01 00:00:00 EDT 1984
· J. Chem. Phys.; (United States)
·
OSTI ID:6398803
Related Subjects
090121 -- Hydrocarbon Fuels-- Chemical Synthesis-- (1976-1989)
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYST SUPPORTS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DATA
DATA ANALYSIS
DEUTERIUM
ELEMENTS
EXPERIMENTAL DATA
FLUIDS
GAMMA SPECTROMETERS
GASES
HIGH TEMPERATURE
HYDROGEN
HYDROGEN ISOTOPES
INFORMATION
IRON
ISOTOPES
KINETICS
LIGHT NUCLEI
MEASURING INSTRUMENTS
METALS
METHANATION
MOESSBAUER SPECTROMETERS
NONMETALS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
OXIDES
OXYGEN
OXYGEN COMPOUNDS
REACTION INTERMEDIATES
REACTION KINETICS
SPECTROMETERS
SPECTROSCOPY
STABLE ISOTOPES
SYNTHESIS GAS
TIME DEPENDENCE
TITANIUM COMPOUNDS
TITANIUM OXIDES
TITRATION
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
10 SYNTHETIC FUELS
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CATALYST SUPPORTS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DATA
DATA ANALYSIS
DEUTERIUM
ELEMENTS
EXPERIMENTAL DATA
FLUIDS
GAMMA SPECTROMETERS
GASES
HIGH TEMPERATURE
HYDROGEN
HYDROGEN ISOTOPES
INFORMATION
IRON
ISOTOPES
KINETICS
LIGHT NUCLEI
MEASURING INSTRUMENTS
METALS
METHANATION
MOESSBAUER SPECTROMETERS
NONMETALS
NUCLEI
NUMERICAL DATA
ODD-ODD NUCLEI
OXIDES
OXYGEN
OXYGEN COMPOUNDS
REACTION INTERMEDIATES
REACTION KINETICS
SPECTROMETERS
SPECTROSCOPY
STABLE ISOTOPES
SYNTHESIS GAS
TIME DEPENDENCE
TITANIUM COMPOUNDS
TITANIUM OXIDES
TITRATION
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS