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Determination of solvation kinetics in supercritical fluids

Technical Report ·
DOI:https://doi.org/10.2172/6306028· OSTI ID:6306028
Objective was to study solvation processes in pure and entrainer-modified supercritical fluids. Specific topics were: Kinetics for solvation in supercritical media, influence on entrainers on solvation, reversibility of solvation, effects of solvation on intramolecular solute-solute interaction kinetics, and impact of fluid density on these processes. Time-resolved fluorescence spectroscopy was used as the main analytical tool. A summary is given of the 2.5 years' research.
Research Organization:
State Univ. of New York, Buffalo, NY (United States). Dept. of Chemistry
Sponsoring Organization:
DOE; USDOE, Washington, DC (United States)
DOE Contract Number:
FG02-90ER14143
OSTI ID:
6306028
Report Number(s):
DOE/ER/14143-2; ON: DE93018923
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400105* -- Separation Procedures
CHROMATOGRAPHY
DOCUMENT TYPES
EMISSION SPECTROSCOPY
FLUORESCENCE SPECTROSCOPY
MICELLAR SYSTEMS
PROGRESS REPORT
SEPARATION PROCESSES
SOLVATION
SPECTROSCOPY
SUPERCRITICAL FLUID CHROMATOGRAPHY
SUPERCRITICAL STATE