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Determination of solvation kinetics in supercritical fluids. Summary report

Technical Report ·
DOI:https://doi.org/10.2172/10172463· OSTI ID:10172463
Objective was to study solvation processes in pure and entrainer-modified supercritical fluids. Specific topics were: Kinetics for solvation in supercritical media, influence on entrainers on solvation, reversibility of solvation, effects of solvation on intramolecular solute-solute interaction kinetics, and impact of fluid density on these processes. Time-resolved fluorescence spectroscopy was used as the main analytical tool. A summary is given of the 2.5 years` research.
Research Organization:
State Univ. of New York, Buffalo, NY (United States). Dept. of Chemistry
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
FG02-90ER14143
OSTI ID:
10172463
Report Number(s):
DOE/ER/14143--2; ON: DE93018923
Country of Publication:
United States
Language:
English