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U.S. Department of Energy
Office of Scientific and Technical Information

Regeneration of spent hydrodesulfurization catalysts employing presulfiding treatment and heteropoly acids

Patent ·
OSTI ID:6305149

The removal of metals, especially vanadium, from spent hydrofining catalyst is accomplished by a two-step process. Treatment with a gaseous sulfur-containing reagent brings the metals to the surface of the catalyst and converts them to sulfides, which are then efficiently removed by contact with a heteropoly acid such as molybdophosphoric acid. Treatment of deactivated hydrodesulfurization catalysts such as Co-Mo supported on alumina by this process results in substantially complete regeneration of catalytic activity.

Assignee:
Exxon Research And Engineering Co
Patent Number(s):
US 4272400
OSTI ID:
6305149
Country of Publication:
United States
Language:
English