Infrared absorption spectroscopy and chemical kinetics of free radicals: Progress report

Technical Report · Wed Mar 01 00:00:00 EST 1989

DOI:https://doi.org/10.2172/6289448· OSTI ID:6289448

Curl, R. F.; Glass, G. P.

Results of the flash photolysis of (A) acetylene and trifluoropropyne, and (B) ammonia are discussed. Reaction mechanisms and vibrationally excited states of CO and CO/sub 2/, resulting from the photolysis of (A) above are addressed. Product branching ratios for NH/sub 2/ and NO between 300 K and 1200 K, resulting from (B) above are also addressed. 2 figs. (CBS)

• Research Organization: Rice Univ., Houston, TX (USA). Dept. of Chemistry
• DOE Contract Number: FG05-85ER13439
• OSTI ID: 6289448
• Report Number(s): DOE/ER/13439-4; ON: DE89010089
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201 -- Chemical & Physicochemical Properties
400500* -- Photochemistry
ACETYLENE
ALKYNES
AMMONIA
CARBON COMPOUNDS
CARBON DIOXIDE
CARBON MONOXIDE
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
DECOMPOSITION
DOCUMENT TYPES
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
EXCITED STATES
HYDRIDES
HYDROCARBONS
HYDROGEN COMPOUNDS
KINETICS
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
NITROGEN OXIDES
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
PHOTOLYSIS
PROGRESS REPORT
PROPYNE
RADICALS
REACTION INTERMEDIATES
REACTION KINETICS
TEMPERATURE EFFECTS
VIBRATIONAL STATES
WATER