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Effect of inhibitors on scale removal in HCl pickling solutions

Journal Article · · Corrosion; (United States)

Inhibitors are available which effectively reduce the loss of metal because of corrosion occurring in the hydrochloric acid pickling baths. Selection of these inhibitors, however, must take into consideration the effect the inhibitor will have on scale dissolution. The optimum concentration of inhibitor must consider the functional relationship between inhibitor concentration and the rate of scale removal. This relationship is not the same as that between inhibitor concentration and metal dissolution rate. Data are shown on scale dissolution rates for 2 corrosion inhibitors in 10% by wt hydrochloric acid at temperatures of 55-85$C (131$-185$F). Extrapolations to somewhat higher temperatures of some pickling operations can be made. However, it was observed that all corrosion inhibitor effects on scale removal became somewhat temperature-dependent at, or near, 80$C. The experimental acid corrosion inhibitors (B and C) exhibit surfactant behavior between 55-75$C, removing scale more quickly than did the uninhibited acid.

Research Organization:
Continental Oil Co; North Texas State Univ
OSTI ID:
6271377
Journal Information:
Corrosion; (United States), Journal Name: Corrosion; (United States) Vol. 24:2; ISSN CORRA
Country of Publication:
United States
Language:
English

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