Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Beneficial role of chloride ions during pickling of steel in sulfuric acid

Journal Article · · Corrosion
DOI:https://doi.org/10.5006/1.3292106· OSTI ID:201377
; ;  [1]
  1. National Metallurgical Lab., Jamshedpur (India). Corrosion Protection Div.

Sodium chloride was shown to have a beneficial effect on the pickling of mild steel in different concentrations of sulfuric acid at various temperatures and ferrous sulfate (FeSO{sub 4}{center_dot}7H{sub 2}O) accumulations in the bath. Addition of this salt to the H{sub 2}SO{sub 4} bath drastically reduced metal loss, enhanced the pickling rate, removed scale quickly, and improved the surface finish of the pickled material. Addition of hydrochloric acid instead of NaCl, however, accelerated the corrosion rate of mild steel in the uninhibited acid solution but had a negligible effect in the inhibited solution. The beneficial effect of NaCl was discussed based upon electrochemical parameters.

Sponsoring Organization:
USDOE
OSTI ID:
201377
Journal Information:
Corrosion, Journal Name: Corrosion Journal Issue: 2 Vol. 52; ISSN 0010-9312; ISSN CORRAK
Country of Publication:
United States
Language:
English

Similar Records

Steel--Project Fact Sheet: Recycling Acid and Metal Salts from Pickling Liquors
Book · Wed Jan 13 23:00:00 EST 1999 · OSTI ID:5838

Effect of inhibitors on scale removal in HCl pickling solutions
Journal Article · Wed Jan 31 23:00:00 EST 1968 · Corrosion; (United States) · OSTI ID:6271377

PICKLING OF THE ZIRCALOYS PRIOR TO CORROSION EXPOSURE
Technical Report · Mon Sep 01 00:00:00 EDT 1958 · OSTI ID:4287130