Chemical probes of charge transfer at semiconductor/liquid junctions. Technical report, January 16, 1985-January 15, 1986
Technical Report
·
OSTI ID:6269543
We attempted to obtain quantitative, non-mass-transfer limited current density vs. potential relationships for a select group of metallocenes. A reproducible procedure for poising the solution redox potential and measuring currents in stirred solutions was developed as well as software programs for data analysis and graphical representation. Even though both p-type and n-type InP electrodes exhibit regions of relative stability, it now appears that this material will not be suitable for detailed kinetic studies. The currents seem to be dominated by leakage phenomena and changes in the thickness of surface oxide which tend to obscure redox processes inherent to the semiconductor solution interface itself.
- Research Organization:
- Colorado Univ., Boulder (USA)
- DOE Contract Number:
- FG02-84ER13247
- OSTI ID:
- 6269543
- Report Number(s):
- DOE/ER/13247-2; ON: DE86005744
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400400* -- Electrochemistry
CHALCOGENIDES
CHEMICAL PREPARATION
ELECTRODES
ELECTRON TRANSFER
ENTROPY
INDIUM COMPOUNDS
INDIUM PHOSPHIDES
KINETICS
MATERIALS
N-TYPE CONDUCTORS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
P-TYPE CONDUCTORS
PHOSPHIDES
PHOSPHORUS COMPOUNDS
PHYSICAL PROPERTIES
PNICTIDES
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
SELENIDES
SELENIUM COMPOUNDS
SEMICONDUCTOR MATERIALS
SYNTHESIS
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS
TUNGSTEN SELENIDES
400400* -- Electrochemistry
CHALCOGENIDES
CHEMICAL PREPARATION
ELECTRODES
ELECTRON TRANSFER
ENTROPY
INDIUM COMPOUNDS
INDIUM PHOSPHIDES
KINETICS
MATERIALS
N-TYPE CONDUCTORS
ORGANIC COMPOUNDS
ORGANOMETALLIC COMPOUNDS
P-TYPE CONDUCTORS
PHOSPHIDES
PHOSPHORUS COMPOUNDS
PHYSICAL PROPERTIES
PNICTIDES
REACTION KINETICS
REFRACTORY METAL COMPOUNDS
SELENIDES
SELENIUM COMPOUNDS
SEMICONDUCTOR MATERIALS
SYNTHESIS
THERMODYNAMIC PROPERTIES
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS
TUNGSTEN SELENIDES