Reactions of bicyclo(2,2. 1)hepta-2,5-diene in the presence of zeolites (in Russian)
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
In the interaction of bicyclo(2.2.1)hepta-2,5-diene with decationized and rare-earth zeolites (H-TsVM, H-Ultrasil, H-mordenite, NaNdY), including the dealuminized NdNaY', wide-pore aluminosilicates and filled zeolite (AShNTs), activated under conditions such that sorbed water remains in (or is added to) the catalyst, alcohols are formed - 3-hydroxynortricyclane and 3-dehydronorborneol - together with ethers 3-(tricyclo(2.2.1.0/sup 2,6/)-3'-heptyloxy)-bicyclo(2.2.1)hept-5-ene and 3,3'-oxydinortricyclane. With aromatic compounds in the presence of wide-pore REE-Y zeolites and also AShNTs, activated at 500/sup 0/C, norbornadiene forms alkylated products such as endo-5-phenyl-2-norbornene from benzene.
- Research Organization:
- Institute of Chemical Physics, Moscow, USSR
- OSTI ID:
- 6226916
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:6; ISSN BACCA
- Country of Publication:
- United States
- Language:
- Russian
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
ALKENES
ALKYLATION
ALUMINIUM COMPOUNDS
ALUMINIUM SILICATES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CYCLOALKENES
DEHYDRATION
ETHERS
HETEROGENEOUS CATALYSIS
HYDROCARBONS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
MATERIALS
MINERALS
MORDENITE
NEODYMIUM COMPOUNDS
NORBORNADIENE
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXYGEN COMPOUNDS
PALLADIUM COMPOUNDS
POROSITY
RARE EARTH COMPOUNDS
SILICATE MINERALS
SILICATES
SILICON COMPOUNDS
SODIUM COMPOUNDS
TEMPERATURE EFFECTS
TRANSITION ELEMENT COMPOUNDS
YIELDS
YTTRIUM COMPOUNDS
ZEOLITES
400201* -- Chemical & Physicochemical Properties
ALKALI METAL COMPOUNDS
ALKENES
ALKYLATION
ALUMINIUM COMPOUNDS
ALUMINIUM SILICATES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CYCLOALKENES
DEHYDRATION
ETHERS
HETEROGENEOUS CATALYSIS
HYDROCARBONS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
MATERIALS
MINERALS
MORDENITE
NEODYMIUM COMPOUNDS
NORBORNADIENE
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
OXYGEN COMPOUNDS
PALLADIUM COMPOUNDS
POROSITY
RARE EARTH COMPOUNDS
SILICATE MINERALS
SILICATES
SILICON COMPOUNDS
SODIUM COMPOUNDS
TEMPERATURE EFFECTS
TRANSITION ELEMENT COMPOUNDS
YIELDS
YTTRIUM COMPOUNDS
ZEOLITES