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Synthesis of 2-(. cap alpha. -alkylaminoethyl)bicyclo(2. 2. 1)heptanes and 2-(. cap alpha. -alkylaminoethyl)bicyclo(2. 2. 2)octanes

Journal Article · · J. Org. Chem. USSR (Engl. Transl.); (United States)
OSTI ID:6136688
; ; ; ;

2-(..cap alpha..-Alkylaminoethyl)bicyclo(2.2.1)heptanes and 2-(..cap alpha..-alkylaminoethyl)bicyclo(2.2.2)octanes were synthesized by the reductive amination of 2-acetylbicyclo(2.2.1)hept-5-ene and 2-acetylbicyclo(2.2.2)oct-5-ene by nitriles in the presence of a copper-magnesium catalyst. The stereochemical composition of the reaction products was determined. The /sup 13/C NMR spectra of all the obtained secondary amines and of the four isomeric 2-(..cap alpha..-hydroxyethyl)bicyclo(2.2.1)heptanes were investigated.

Research Organization:
Institute of Physical Organic Chemistry, Minsk, USSR
OSTI ID:
6136688
Journal Information:
J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 21:12; ISSN JOCYA
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKALINE EARTH METAL COMPOUNDS
ALKANES
ALKENES
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
AMINATION
AMINES
CARBON 13
CARBON ISOTOPES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHALCOGENIDES
CHEMICAL REACTIONS
CHEMICAL SHIFT
COMPLEXES
CONFORMATIONAL CHANGES
COPPER
COPPER COMPOUNDS
COPPER OXIDES
CYCLOALKANES
CYCLOALKENES
DEHYDROGENATION
ELEMENTS
EUROPIUM COMPLEXES
EVEN-ODD NUCLEI
HALIDES
HALOGEN COMPOUNDS
HEPTANE
HETEROGENEOUS CATALYSIS
HYDROCARBONS
HYDROGEN 1
HYDROGEN ISOTOPES
HYDROGENATION
IODIDES
IODINE COMPOUNDS
ISOMERIZATION
ISOTOPES
KETONES
LIGHT NUCLEI
MAGNESIUM COMPOUNDS
MAGNESIUM IODIDES
MAGNESIUM OXIDES
MATERIALS TESTING
METALS
NITRILES
NMR SPECTRA
NUCLEI
OCTANE
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RARE EARTH COMPLEXES
RELAXATION
RELAXATION TIME
SPECTRA
SPIN-LATTICE RELAXATION
STABLE ISOTOPES
STEREOCHEMISTRY
SYNTHESIS
TESTING
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
YTTERBIUM COMPLEXES
ZINC