Hydrocarboxylation of olefins in the presence of Pd(II) complexes (in Russian)
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
The rate and selectivity of hydrocarboxylation of terminal olefins in dioxane with catalysis by the PdCl/sub 2/(PPh/sub 3/)/sub 2/-PPh/sub 3/ system increases in the series C/sub 3/ < C/sub 5/ < C/sub 7/, C/sub 9/; under the mentioned conditions, the hydrocarboxylation of olefins with an internal double bond occurs significantly slower than the hydrocarboxylation of terminal olefins. The replacement of PPh/sub 3/ by SnCl/sub 2/ promotes an increase of the rate and selectivity of hydrocarboxylation of terminal olefins by PdCl/sub 2/(PPh/sub 3/)/sub 2/-SnCl/sub 2/ system and sharply retards carbonylation of olefins with an internal double bond. The side process of displacement of the double bond in 1-pentene practically does not affect the selectivity of hydrocarboxylation of this olefin in the presence of PdCl/sub 2/ x (PPh/sub 3/)/sub 2/-SnCl/sub 2/.
- Research Organization:
- L.Ya. Karpov Physicochemical Institute, Moscow, USSR
- OSTI ID:
- 6226842
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:5; ISSN BACCA
- Country of Publication:
- United States
- Language:
- Russian
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ALKENES
CARBONYLATION
CARBOXYLATION
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DIOXANE
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
ISOMERIZATION
ISOMERS
KINETICS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
QUANTITY RATIO
REACTION KINETICS
TIN CHLORIDES
TIN COMPOUNDS
TIN HALIDES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
400201* -- Chemical & Physicochemical Properties
ALKENES
CARBONYLATION
CARBOXYLATION
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL BONDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
DIOXANE
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
ISOMERIZATION
ISOMERS
KINETICS
ORGANIC COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
PHOSPHINES
PHOSPHORUS COMPOUNDS
QUANTITY RATIO
REACTION KINETICS
TIN CHLORIDES
TIN COMPOUNDS
TIN HALIDES
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS