Trisacetylacetonates of cobalt(II) and nickel(II) with the tetrabutylammonium cation at the outer sphere

Journal Article · Sun Nov 09 23:00:00 EST 1986 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00955341· OSTI ID:6226746

Steblyanko, A Yu; Grigor'ev, A N; Martynenko, L I; Spitsyn, V I

The trisacetylacetonates of cobalt and nickel with the tetrabutylammonium cation in the outer sphere have been synthesized by the interaction of tetrabutylammonium hydroxide, acetylacetone, and the dihydrates of cobalt and nickel bisacetylacetonates. The nickel complex is thermally more stable than the cobalt complex. When heated in vacuum, both complexes decompose into tetrabutylammonium acetylacetonate and anhydrous acetylacetonates of cobalt(II) and nickel(II).

• Research Organization: M.V. Lomonosov Moscow State Univ., USSR
• OSTI ID: 6226746
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Journal Name: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States) Vol. 35:5; ISSN BACCA
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
360602 -- Other Materials-- Structure & Phase Studies
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ACETYLACETONE
AMINES
AMMONIUM COMPOUNDS
AMMONIUM HYDROXIDES
CATALYSTS
CATALYTIC EFFECTS
CATIONS
CHARGED PARTICLES
CHELATING AGENTS
CHEMICAL BONDS
CHEMICAL REACTIONS
COBALT COMPLEXES
COHERENT SCATTERING
COMPLEXES
COMPLEXOMETRY
CRYSTALLIZATION
DECOMPOSITION
DIFFRACTION
DISSOCIATION
EVAPORATION
HYDRATES
HYDROGEN COMPOUNDS
HYDROXIDES
INFRARED SPECTRA
IONS
KETONES
MAGNETIC PROPERTIES
MAGNETIC SUSCEPTIBILITY
NICKEL COMPLEXES
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
PHASE TRANSFORMATIONS
PHYSICAL PROPERTIES
PYROLYSIS
QUATERNARY COMPOUNDS
REAGENTS
SCATTERING
SPECTRA
SUBLIMATION
SYNTHESIS
TEMPERATURE EFFECTS
THERMOCHEMICAL PROCESSES
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION