Thin-layer chromatographic separation of optical, geometrical, and structural isomers
Journal Article
·
· Anal. Chem.; (United States)
A number of different silica gels and binders were evaluated in the development of a ..beta..-cyclodextrin bonded TLC phase with the capability to separate enantiomeric compounds. Planar chromatographic conditions were optimized for the separation of nine racemic mixtures, three diastereomeric mixtures, and six structural isomers. Mobile phases and elution behavior of all solutes were analogous to the related LC technique indicating the two methods are sufficiently compatible to be used in conjuction with one another. This should provide one with much greater flexibility in the field of isomeric separations. 12 references, 2 figures, 2 tables.
- Research Organization:
- Texas Technical Univ., Lubbock
- DOE Contract Number:
- AS05-84ER13159
- OSTI ID:
- 6207446
- Journal Information:
- Anal. Chem.; (United States), Journal Name: Anal. Chem.; (United States) Vol. 58:3; ISSN ANCHA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400105* -- Separation Procedures
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ADSORBENTS
ADSORPTION
CHROMATOGRAPHY
DATA
ELUTRIATION
EXPERIMENTAL DATA
INFORMATION
ISOMERS
NUMERICAL DATA
PHASE STUDIES
RACEMATES
SEPARATION PROCESSES
SILICA GEL
SOLUTES
SORPTION
SORPTIVE PROPERTIES
SURFACE PROPERTIES
THIN-LAYER CHROMATOGRAPHY
400105* -- Separation Procedures
400301 -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
ADSORBENTS
ADSORPTION
CHROMATOGRAPHY
DATA
ELUTRIATION
EXPERIMENTAL DATA
INFORMATION
ISOMERS
NUMERICAL DATA
PHASE STUDIES
RACEMATES
SEPARATION PROCESSES
SILICA GEL
SOLUTES
SORPTION
SORPTIVE PROPERTIES
SURFACE PROPERTIES
THIN-LAYER CHROMATOGRAPHY