Lithium/molybdenum oxysulfide secondary batteries

Journal Article · Wed Feb 01 04:00:00 EST 1989 · J. Electrochem. Soc.; (United States)

DOI:https://doi.org/10.1149/1.2096686· OSTI ID:6200479

Abraham, K M; Pasquariello, D M; Willstaedt, E B

The authors have discovered that amorphous molybdenum oxysulfides are useful as cathode materials for ambient temperature rechargeable Li batteries. Two molybdenum oxysulfides, MoOS/sub 2/ and MoO/sub 2/S, were prepared, characterized by physical and chemical means, and evaluated as Li battery cathodes. Laboratory test cells containing either MoOS/sub 2/ or MoO/sub 2/S delivered more than 100 deep discharge/charge cycles. While there is significant current effort in the development of Li/TiS/sub 2/ and Li/MoS/sub 2/ secondary cells, the search for positive electrode materials with higher specific energies has continued. In this regard, molybdenum chalcogenides have received a great deal of attention. They include the Chevrel phases of general formula M/sub y/Mo/sub 6/X/sub 8/ (M = metallic element, X = chalcogen), amorphous MoS/sub 3/, Mo/sub 2/S/sub 5/ and MoSe/sub 3/S. This investigation represents an extention of the search for improved secondary Li battery cathode materials to a hitherto unexplored class of Mo compounds, namely molybdenum oxysulfides.

• Research Organization: EIC Labs., Inc., Norwood, MA (US)
• OSTI ID: 6200479
• Journal Information: J. Electrochem. Soc.; (United States), Journal Name: J. Electrochem. Soc.; (United States) Vol. 136:2; ISSN JESOA
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
250901 -- Energy Storage-- Batteries-- Design & Development
250903* -- Energy Storage-- Batteries-- Materials
Components
& Auxiliaries
AMBIENT TEMPERATURE
AMORPHOUS STATE
ANODES
CATHODES
CHALCOGENIDES
ELECTRIC BATTERIES
ELECTROCHEMICAL CELLS
ELECTRODES
LITHIUM-SULFUR BATTERIES
MATERIALS TESTING
METAL-NONMETAL BATTERIES
MOLYBDENUM COMPOUNDS
MOLYBDENUM SULFIDES
REFRACTORY METAL COMPOUNDS
RESEARCH PROGRAMS
SULFIDES
SULFUR COMPOUNDS
TESTING
TRANSITION ELEMENT COMPOUNDS