Generation of binuclear (d/sup 8/. d/sup 8/)psigma platinum and rhodium complexes by pulse radiolysis
Journal Article
·
· J. Am. Chem. Soc.; (United States)
Two (d/sup 8/.d/sup 8/)psigma binuclear complexes, Pt/sub 2/(pop)/sub 4//sup 5 -/ (pop = P/sub 2/O/sub 5/H/sub 2//sup 2 -/) and Rh/sub 2/(TMB)/sub 4//sup +/ (TMB = 2,5-dimethyl-2,5-diisocyanohexane), have been generated by pulse radiolysis of aqueous and acetonitrile solutions, respectively, of the corresponding d/sup 8/.d/sup 8/ species. An intense absorption system attributable to the allowed dsigma* ..-->.. psigma transition is observed in the spectrum of each of the transients (420 nm, Pt/sub 2/(pop)/sub 4//sup 5 -/; 570 nm, Rh/sub 2/(TMB)/sub 4//sup +/).
- Research Organization:
- California Inst. of Tech., Pasadena
- OSTI ID:
- 6199691
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 106:18; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
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Wed Apr 30 00:00:00 EDT 1986
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5532301
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Journal Article
·
Wed Oct 22 00:00:00 EDT 1980
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6904000
Spectroscopic properties and redox chemistry of the phosphorescent excited state of Pt/sub 2/(P/sub 2/O/sub 5/)/sub 4/H/sub 8//sup 4 -/
Journal Article
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Tue Dec 29 23:00:00 EST 1981
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5225469
Related Subjects
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
400600* -- Radiation Chemistry
ABSORPTION SPECTROSCOPY
ACETONITRILE
AQUEOUS SOLUTIONS
CHEMICAL PREPARATION
CHEMICAL RADIATION EFFECTS
CHEMISTRY
COMPLEXES
DATA
DISPERSIONS
EXPERIMENTAL DATA
INFORMATION
IRRADIATION
MIXTURES
NITRILES
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
PLATINUM COMPLEXES
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RHODIUM COMPLEXES
SOLUTIONS
SPECTROSCOPY
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400600* -- Radiation Chemistry
ABSORPTION SPECTROSCOPY
ACETONITRILE
AQUEOUS SOLUTIONS
CHEMICAL PREPARATION
CHEMICAL RADIATION EFFECTS
CHEMISTRY
COMPLEXES
DATA
DISPERSIONS
EXPERIMENTAL DATA
INFORMATION
IRRADIATION
MIXTURES
NITRILES
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
PLATINUM COMPLEXES
PULSED IRRADIATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RHODIUM COMPLEXES
SOLUTIONS
SPECTROSCOPY
SYNTHESIS
TRANSITION ELEMENT COMPLEXES