Temporary anion states of. pi. -ligand transition-metal carbonyls studied by means of electron transmission spectroscopy and x. cap alpha. calculations
Journal Article
·
· J. Am. Chem. Soc.; (United States)
The resonances observed in the electron transmission spectra of (benzene)chromium tricarbonyl, (cyclopentadienyl)manganese tricarbonyl, (1,3-butadiene)iron tricarbonyl, and (cyclopentadienyl)cobalt dicarbonyl have been assigned with the aid of MS X..cap alpha.. calculations. In contrast with previous theoretical results, the present calculations on the neutral states show a large net electronic charge transfer from the ..pi.. ligand to the metal.
- Research Organization:
- Universita di Bologna, Italy
- OSTI ID:
- 6181972
- Journal Information:
- J. Am. Chem. Soc.; (United States), Journal Name: J. Am. Chem. Soc.; (United States) Vol. 109:15; ISSN JACSA
- Country of Publication:
- United States
- Language:
- English
Similar Records
Evaluuation of the strength of the metal-ligand bond in manganese and rhenium carbonyl complexes with condensed. pi. -ligands
Characterization of the temporary anion states of metal carbonyl complexes: an MS-X. cap alpha. and ETS study of Cr(CO)/sub 6/ and Fe(CO)/sub 5/
Effect of an N-N chelate ligand on the insertion reactions of carbon monoxide into a manganese--alkyl bond
Journal Article
·
Fri Feb 28 23:00:00 EST 1986
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
·
OSTI ID:7032343
Characterization of the temporary anion states of metal carbonyl complexes: an MS-X. cap alpha. and ETS study of Cr(CO)/sub 6/ and Fe(CO)/sub 5/
Journal Article
·
Tue Jan 19 23:00:00 EST 1988
· J. Am. Chem. Soc.; (United States)
·
OSTI ID:5523060
Effect of an N-N chelate ligand on the insertion reactions of carbon monoxide into a manganese--alkyl bond
Journal Article
·
Sat Aug 01 00:00:00 EDT 1992
· Organometallics
·
OSTI ID:555001
Related Subjects
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AFFINITY
ANIONS
CARBONYLS
CHARGED PARTICLES
CHROMIUM COMPLEXES
COBALT COMPLEXES
COMPLEXES
DATA
ELECTRON MICROSCOPY
ELECTRONIC STRUCTURE
ENERGY RANGE
EV RANGE
EV RANGE 01-10
EXPERIMENTAL DATA
INFORMATION
IONS
IRON COMPLEXES
MANGANESE COMPLEXES
MATHEMATICAL MODELS
MICROSCOPY
MOLECULAR MODELS
MOLECULAR STRUCTURE
NUMERICAL DATA
SPECTROSCOPY
THEORETICAL DATA
TRANSITION ELEMENT COMPLEXES
TRANSMISSION ELECTRON MICROSCOPY
400201* -- Chemical & Physicochemical Properties
AFFINITY
ANIONS
CARBONYLS
CHARGED PARTICLES
CHROMIUM COMPLEXES
COBALT COMPLEXES
COMPLEXES
DATA
ELECTRON MICROSCOPY
ELECTRONIC STRUCTURE
ENERGY RANGE
EV RANGE
EV RANGE 01-10
EXPERIMENTAL DATA
INFORMATION
IONS
IRON COMPLEXES
MANGANESE COMPLEXES
MATHEMATICAL MODELS
MICROSCOPY
MOLECULAR MODELS
MOLECULAR STRUCTURE
NUMERICAL DATA
SPECTROSCOPY
THEORETICAL DATA
TRANSITION ELEMENT COMPLEXES
TRANSMISSION ELECTRON MICROSCOPY