Effect of an N-N chelate ligand on the insertion reactions of carbon monoxide into a manganese--alkyl bond
- Universidad de Oviedo (Spain); and others
The insertion of carbon monoxide into metal-alkyl bonds has been extensively investigated as acyl complexes are involved in many catalytic and stoichiometric carbonylation reactions in the laboratory and in industry. We report here the reactions of alkyl tricarbonyl complexes of manganese containing N-N chelate ligands with two-electron donor ligands to afford acyl tri- or dicarbonyl derivatives to examine the influence of ancillary ligands. 22 refs., 2 figs., 1 tab.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 555001
- Journal Information:
- Organometallics, Journal Name: Organometallics Journal Issue: 8 Vol. 11; ISSN ORGND7; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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