sup 31 P and sup 195 Pt NMR data of several T-frame diplatinum complexes that exhibit unusual structure, bonding, and reactivity
Journal Article
·
· Inorganic Chemistry; (USA)
- Vanderbilt Univ., Nashville, TN (USA)
The authors have previously reported the synthesis, structure, and bonding of several new dinuclear complexes including seven diplatinum complexes. The analysis of the {sup 31}P and {sup 195}Pt NMR spectra of these complexes is presented herein. These data have considerable diagnostic values for determining the formation of diplatinum complexes of this structural type and may lead to a better understanding of the usual electronic structure of these molecules. 12 refs., 1 tab.
- OSTI ID:
- 6178756
- Journal Information:
- Inorganic Chemistry; (USA), Vol. 29:15; ISSN 0020-1669
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:6178756
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/195/Pt(/sup 1/H) and /sup 31/P(/sup 1/H) NMR investigation of the platinum(0)-tetraphosphine complexes Pt(CH/sub 3/C(CH/sub 2/PPh/sub 2/)/sub 3/)PR/sub 3/
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OSTI ID:6178756
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OSTI ID:6178756
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AROMATICS
ELECTRONIC STRUCTURE
HALOGEN COMPOUNDS
PLATINUM COMPLEXES
EXPERIMENTAL DATA
NMR SPECTRA
PHOSPHORUS 31
PLATINUM 195
COMPLEXES
DATA
DAYS LIVING RADIOISOTOPES
EVEN-ODD NUCLEI
HEAVY NUCLEI
INFORMATION
INTERNAL CONVERSION RADIOISOTOPES
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
PHOSPHORUS ISOTOPES
PLATINUM ISOTOPES
RADIOISOTOPES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AROMATICS
ELECTRONIC STRUCTURE
HALOGEN COMPOUNDS
PLATINUM COMPLEXES
EXPERIMENTAL DATA
NMR SPECTRA
PHOSPHORUS 31
PLATINUM 195
COMPLEXES
DATA
DAYS LIVING RADIOISOTOPES
EVEN-ODD NUCLEI
HEAVY NUCLEI
INFORMATION
INTERNAL CONVERSION RADIOISOTOPES
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
PHOSPHORUS ISOTOPES
PLATINUM ISOTOPES
RADIOISOTOPES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation