/195/Pt(/sup 1/H) and /sup 31/P(/sup 1/H) NMR investigation of the platinum(0)-tetraphosphine complexes Pt(CH/sub 3/C(CH/sub 2/PPh/sub 2/)/sub 3/)PR/sub 3/
Preparation of a series of dissociatively stable Pt(tripod)PR/sub 3/ complexes where tripod = CH/sub 3/C(CH/sub 2/PPh/sub 2/)/sub 3/ and PR/sub 3/ = PMe/sub 2/Ph, PMePh/sub 2/, PPh/sub 3/, P(4FC/sub 6/H/sub 4/)/sub 3/, P(3,5(CF/sub 3/)/sub 2/C/sub 6/H/sub 3/)/sub 3/, P(CH/sub 2/CH/sub 2/CN)/sub 3/, P(OMe)Ph/sub 2/, P(OMe)/sub 2/Ph, P(OMe)/sub 3/, P(POh)/sub 3/, and P(OCH/sub 2/CF/sub 3/)/sub 3/ are reported. /sup 195/Pt(/sup 1/H) and /sup 31/P(/sup 1/H) NMR data are also included. These data have expanded the data base available for the platinum (0) complexes and facilitated the drawing of empirical relationships from the platinum chemical shifts and platinum-phosphorus coupling constants. 29 refs., 1 fig., 1 tab.
- Research Organization:
- Ohio State Univ., Columbus (USA)
- OSTI ID:
- 5832974
- Journal Information:
- Inorg. Chem.; (United States), Vol. 27:9
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CYCLOALKENES
CHEMICAL PREPARATION
ORGANIC FLUORINE COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PLATINUM COMPLEXES
EXPERIMENTAL DATA
NUCLEAR MAGNETIC RESONANCE
PHOSPHORUS 31
PLATINUM 195
PROTONS
ALKENES
BARYONS
COMPLEXES
DATA
DAYS LIVING RADIOISOTOPES
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
FERMIONS
HADRONS
HEAVY NUCLEI
HYDROCARBONS
INFORMATION
INTERNAL CONVERSION RADIOISOTOPES
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
LIGHT NUCLEI
MAGNETIC RESONANCE
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
PHOSPHORUS ISOTOPES
PLATINUM ISOTOPES
RADIOISOTOPES
RESONANCE
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation