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/195/Pt(/sup 1/H) and /sup 31/P(/sup 1/H) NMR investigation of the platinum(0)-tetraphosphine complexes Pt(CH/sub 3/C(CH/sub 2/PPh/sub 2/)/sub 3/)PR/sub 3/

Journal Article · · Inorg. Chem.; (United States)
DOI:https://doi.org/10.1021/ic00282a030· OSTI ID:5832974
; ;
Preparation of a series of dissociatively stable Pt(tripod)PR/sub 3/ complexes where tripod = CH/sub 3/C(CH/sub 2/PPh/sub 2/)/sub 3/ and PR/sub 3/ = PMe/sub 2/Ph, PMePh/sub 2/, PPh/sub 3/, P(4FC/sub 6/H/sub 4/)/sub 3/, P(3,5(CF/sub 3/)/sub 2/C/sub 6/H/sub 3/)/sub 3/, P(CH/sub 2/CH/sub 2/CN)/sub 3/, P(OMe)Ph/sub 2/, P(OMe)/sub 2/Ph, P(OMe)/sub 3/, P(POh)/sub 3/, and P(OCH/sub 2/CF/sub 3/)/sub 3/ are reported. /sup 195/Pt(/sup 1/H) and /sup 31/P(/sup 1/H) NMR data are also included. These data have expanded the data base available for the platinum (0) complexes and facilitated the drawing of empirical relationships from the platinum chemical shifts and platinum-phosphorus coupling constants. 29 refs., 1 fig., 1 tab.
Research Organization:
Ohio State Univ., Columbus (USA)
OSTI ID:
5832974
Journal Information:
Inorg. Chem.; (United States), Journal Name: Inorg. Chem.; (United States) Vol. 27:9; ISSN INOCA
Country of Publication:
United States
Language:
English

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Journal Article · Sat Dec 31 23:00:00 EST 1983 · Inorg. Chem.; (United States) · OSTI ID:6729776
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Journal Article · Thu Dec 31 23:00:00 EST 1987 · Organometallics; (United States) · OSTI ID:7148476

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
400202 -- Isotope Effects
Isotope Exchange
& Isotope Separation
ALKENES
BARYONS
CHEMICAL PREPARATION
COMPLEXES
CYCLOALKENES
DATA
DAYS LIVING RADIOISOTOPES
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
EXPERIMENTAL DATA
FERMIONS
HADRONS
HEAVY NUCLEI
HYDROCARBONS
INFORMATION
INTERNAL CONVERSION RADIOISOTOPES
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
LIGHT NUCLEI
MAGNETIC RESONANCE
NUCLEAR MAGNETIC RESONANCE
NUCLEI
NUCLEONS
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
ORGANOMETALLIC COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PLATINUM 195
PLATINUM COMPLEXES
PLATINUM ISOTOPES
PROTONS
RADIOISOTOPES
RESONANCE
STABLE ISOTOPES
SYNTHESIS
TRANSITION ELEMENT COMPLEXES