Influence of solvent on conformational equilibrium in phenyl glycidyl ether

Journal Article · Sun Sep 01 00:00:00 EDT 1985 · Theor. Exp. Chem. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00945206· OSTI ID:6136313

Chervinskii, A Yu; Shologon, I M; Kapkan, L M; Klebanov, M S

The conformational equilibrium in phenyl glycidyl ether in aprotic solvents was studied by the PMR method over a broad range of changes in the values of the dielectric constant. It was shown that the parameters of the multiplet of noncyclic methylene protons in the PMR spectrum of phenyl glycidyl ether are a sensitive indicator of the position of the conformation equilibrium in the glycidyl fragment. The specific interaction of the molecules of aromatic solvents with the epoxide ring has been discovered.

• Research Organization: Institute of Physical Organic Chemistry, Donetsk, USSR
• OSTI ID: 6136313
• Journal Information: Theor. Exp. Chem. (Engl. Transl.); (United States), Journal Name: Theor. Exp. Chem. (Engl. Transl.); (United States) Vol. 21:2; ISSN TEXCA
• Country of Publication: United States
• Language: Russian

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
640302 -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ACTIVATION ENERGY
ALKYLATED AROMATICS
AROMATICS
BENZENE
CARBON TETRACHLORIDE
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLORINATED AROMATIC HYDROCARBONS
CHLOROFORM
CONFORMATIONAL CHANGES
COUPLING
COUPLING CONSTANTS
DIELECTRIC PROPERTIES
ELECTRICAL PROPERTIES
ELECTRONIC STRUCTURE
ENERGY
ETHERS
HALOGENATED ALIPHATIC HYDROCARBONS
HALOGENATED AROMATIC HYDROCARBONS
HYDROCARBONS
INTERMEDIATE COUPLING
J-J COUPLING
MATERIALS TESTING
MESITYLENE
METHYLENE CHLORIDE
MOLECULAR STRUCTURE
NITRILES
NITRO COMPOUNDS
NITROBENZENE
NMR SPECTRA
NUCLEAR SCREENING
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SOLVENTS
PHYSICAL PROPERTIES
SCREENING
SOLVENTS
SPECTRA
TESTING
TOLUENE
XYLENE-PARA
XYLENES