Epoxy resin cure. [Phenyl glycidyl ether]

Technical Report · Tue Jul 01 00:00:00 EDT 1986

OSTI ID:5533022

Smith, R E; Woodburn, G L

The reactions that occur between the model epoxy, phenyl glycidyl ether, and the cure agent dicyandiamide (DICY) have been investigated using nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), gel permeation chromatography (GPC), and high-performance liquid chromatography (HPLC) techniques. It is shown that the reaction at 130/sup 0/C requires 90 min for completion when catalyzed by boron trifluoride monoethyl amine (BF/sub 3/-MEA). At least three major products are formed. The identity of these products is based on previously published spectroscopic data. 3 refs., 5 figs.

• Research Organization: Allied Corp., Kansas City, MO (USA). Bendix Kansas City Div.
• DOE Contract Number: AC04-76DP00613
• OSTI ID: 5533022
• Report Number(s): BDX-613-3551; ON: DE86013613
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987)
BORON COMPOUNDS
BORON FLUORIDES
CARBONIC ACID DERIVATIVES
CATALYTIC EFFECTS
CHEMICAL REACTIONS
CHROMATOGRAPHY
CURING
CYANAMIDES
DATA
EPOXIDES
ETHERS
EXPERIMENTAL DATA
FLUORIDES
FLUORINE COMPOUNDS
GEL PERMEATION CHROMATOGRAPHY
HALIDES
HALOGEN COMPOUNDS
HIGH TEMPERATURE
INFORMATION
INFRARED SPECTRA
LIQUID COLUMN CHROMATOGRAPHY
MAGNETIC RESONANCE
NUCLEAR MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC POLYMERS
PETROCHEMICALS
PETROLEUM PRODUCTS
PHENYL ETHER
POLYMERS
RESINS
RESONANCE
SEPARATION PROCESSES
SPECTRA