Reactions of amino and thio derivatives of polyfluorinated. beta. -diketones with amines

Journal Article · Wed Dec 10 04:00:00 EST 1986 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6135740

Busygin, I G; Paskhevich, K I

A study was carried out on the aminolysis of isomeric polyfluorinated ..beta..-aminovinylthiones and monothio-..beta..-diketones with geminal fluoroalkyl and mercapto groups. ..beta..-Aminovinylthiones react with amines at the enamine electrophilic site, while monothio-..beta..-diketones react at the electrophilic site attached to the nonfluorinated substituent. Intrachelate prototropic tautomerism is presumably one of the factors responsible for the reaction regiospecificity.

• Research Organization: Institute of Chemistry, Sverdlovsk, USSR
• OSTI ID: 6135740
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States) Vol. 22:7; ISSN JOCYA
• Country of Publication: United States
• Language: Russian

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400202* -- Isotope Effects
Isotope Exchange
& Isotope Separation
AMINATION
AMINES
AMMONIA
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTIONS
CHEMICAL SHIFT
CHLORINATED ALIPHATIC HYDROCARBONS
CHLOROFORM
CHROMATOGRAPHY
DEUTERATION
DEUTERIUM
DEUTERIUM COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDRIDES
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
HYDROGEN TRANSFER
INFRARED SPECTRA
INORGANIC ACIDS
ISOMERIZATION
ISOTOPE EFFECTS
ISOTOPES
ISOTOPIC EXCHANGE
KETONES
KINETICS
LIGHT NUCLEI
NITROGEN COMPOUNDS
NITROGEN HYDRIDES
NMR SPECTRA
NUCLEI
ODD-ODD NUCLEI
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
REACTION KINETICS
SEPARATION PROCESSES
SPECTRA
STABLE ISOTOPES
SULFURIC ACID
THIN-LAYER CHROMATOGRAPHY
THIOLS