Reactions of the Xe(/sup 3/P/sub 1/) resonance states with halogen donor molecules
Journal Article
·
· J. Phys. Chem.; (United States)
OSTI ID:6122288
The formation of KrX* and XeX* (X=F, Cl, Br, and I) from the reaction of the (/sup 3/P/sub 1/) resonance states of the rare gases with halogen donors is reported. The experimental procedure is described. The low pressure emission spectra of XeX and KrX from these reactions are compared to that from the (/sup 3/P/sub 2/) metastable atom reactions. Relative rate constants are estimated for formation of the B and C states of XeCl for a series of chlorinated reagents. From the pressure dependence of the XeCl and XeF B/C ratios, values are assigned for the transfer rate constants for He, Ne, and Ar bath gases. (BLM)
- Research Organization:
- Kansas State Univ., Manhattan
- OSTI ID:
- 6122288
- Journal Information:
- J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 84:2; ISSN JPCHA
- Country of Publication:
- United States
- Language:
- English
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