Reactions of the Xe(/sup 3/P/sub 1/) and Kr(/sup 3/P/sub 1/) resonance states with halogen donor molecules

Journal Article · Thu Jan 24 04:00:00 EST 1980 · J. Phys. Chem.; (United States)

OSTI ID:5075296

Sehgal, C; Sutherland, R G; Verrall, R E

This communication reports the formation of KrX and XeX (X = F, Cl, Br) from the reaction of the (/sup 3/P/sub 1/) resonance states with halogen donors. The low pressure XeX and KrX emission spectra from these reactions are compared to those from the (/sup 3/P/sub 2/) metastable atom reactions. Relative rate constants for the formation of XeCl B and C states are estimated for a series of chlorinated reagants. From the pressure dependence of the XeCl and XeF B/C ratio, transfer rate constants are assigned for helium, neon, and argon bath gases. 17 references, 2 figures.

• Research Organization: Univ. of Saskatchewan, Saskatoon
• OSTI ID: 5075296
• Journal Information: J. Phys. Chem.; (United States), Journal Name: J. Phys. Chem.; (United States) Vol. 84:2; ISSN JPCHA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
ARGON
BROMIDES
BROMINE
BROMINE COMPOUNDS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE
CHLORINE COMPOUNDS
DATA
ELECTROMAGNETIC RADIATION
ELEMENTS
EMISSION SPECTRA
EXPERIMENTAL DATA
FLUIDS
FLUORIDES
FLUORINE
FLUORINE COMPOUNDS
GASES
HALIDES
HALOGEN COMPOUNDS
HALOGENS
HELIUM
HIGH VACUUM
INERT ATMOSPHERE
INFORMATION
KINETICS
KRYPTON
KRYPTON BROMIDES
KRYPTON CHLORIDES
KRYPTON COMPOUNDS
KRYPTON FLUORIDES
LASER RADIATION
LOW PRESSURE
MEDIUM PRESSURE
MEDIUM VACUUM
NEON
NONMETALS
NUMERICAL DATA
PRESSURE DEPENDENCE
RADIATIONS
RARE GAS COMPOUNDS
RARE GASES
REACTION KINETICS
SPECTRA
ULTRAHIGH VACUUM
XENON
XENON BROMIDES
XENON CHLORIDES
XENON COMPOUNDS
XENON FLUORIDES
YIELDS