Band transition moments between excited singlet states of the H/sub 2/ molecule, nonadiabatic eigenvectors, and probabilities for spontaneous emission
Journal Article
·
· At. Data Nucl. Data Tables; (United States)
The electronic dipole transition moments of Wolniewicz are used to calculate the vibrational-electronic band transition moments and probabilities for spontaneous emission in the adiabatic and nonadiabatic approximations for the H/sub 2/ molecule in the (EF,GK,HH)/sup 1/..sigma../sup +//sub g/-(B,B') /sup 1/..sigma../sup +//sub u/,C/sup 1/Pi/sub u/ systems. The electronic integrals over the nuclear-momentum operators which describe the nonadiabatic coupling within the J = 0 states of EF, GK, and HH /sup 1/..sigma../sup +//sub g/, computed by Wolniewicz, are used to obtain nonadiabatic vibrational-electronic /sup 1/..sigma../sup +//sub g/ eigenfunctions.
- Research Organization:
- Laboratoire de Spectroscopie Hertzienne de l'E.N.S., Universite Pierre et Marie Curie, 75230 Paris Cedex 05, France
- OSTI ID:
- 6093554
- Journal Information:
- At. Data Nucl. Data Tables; (United States), Journal Name: At. Data Nucl. Data Tables; (United States) Vol. 30:2; ISSN ADNDA
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
640302* -- Atomic
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ADIABATIC APPROXIMATION
E1-TRANSITIONS
ELEMENTS
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
EXCITED STATES
HYDROGEN
MOLECULES
MULTIPOLE TRANSITIONS
NONMETALS
PROBABILITY
VIBRATIONAL STATES
Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory
74 ATOMIC AND MOLECULAR PHYSICS
ADIABATIC APPROXIMATION
E1-TRANSITIONS
ELEMENTS
ENERGY LEVELS
ENERGY-LEVEL TRANSITIONS
EXCITED STATES
HYDROGEN
MOLECULES
MULTIPOLE TRANSITIONS
NONMETALS
PROBABILITY
VIBRATIONAL STATES