Synthesis of derivatives of indole and quinoline by the intramolecular catalytic cyclization of allylanilines

Journal Article · Mon Sep 01 00:00:00 EDT 1986 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

DOI:https://doi.org/10.1007/BF00514991· OSTI ID:6085468

Abdrakmanov, I B; Mustafin, A G; Tolstikov, G A; Fakhretdinov, R N; Dzhemilev, U M

An effective method for the isolation of 3-methyl-2-ethylindole and 2,4-dimethyl-quinoline by the intramolecular cyclization of N-(1-methyl-2-butenyl)- and 2-(1-methyl-2-butenyl)anilines under the action of the catalyst PdCl/sub 2/ (DMSO)/sub n/ was developed. The influence of the nature of the solvent, the temperature, and the concentration of the catalyst on the yield and the ratio of the reaction products was investigated.

• Research Organization: Institute of Chemistry, Ufa, USSR
• OSTI ID: 6085468
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Journal Name: Chem. Heterocycl. Compd. (Engl. Transl.); (United States) Vol. 22:3; ISSN CHCCA
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
400201* -- Chemical & Physicochemical Properties
AMIDES
AMINES
AROMATICS
AZAARENES
AZINES
AZOLES
CATALYSIS
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL REACTION YIELD
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
CHROMATOGRAPHY
COMPLEXES
DEHYDROCYCLIZATION
DMSO
FORMAMIDE
FURANS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
HOMOGENEOUS CATALYSIS
INDOLES
INFRARED SPECTRA
MULTIPLETS
NITRILES
NITRO COMPOUNDS
NITROBENZENE
NMR SPECTRA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SOLVENTS
ORGANIC SULFUR COMPOUNDS
PALLADIUM CHLORIDES
PALLADIUM COMPLEXES
PALLADIUM COMPOUNDS
PYRIDINES
PYRROLES
QUANTITY RATIO
QUINOLINES
SEPARATION PROCESSES
SOLVENT PROPERTIES
SOLVENTS
SPECTRA
STOICHIOMETRY
SULFOXIDES
SYNTHESIS
TEMPERATURE DEPENDENCE
TETRAHYDROFURAN
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS