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U.S. Department of Energy
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Low-pressure approach to the formation and study of exciplex systems. Final report

Technical Report ·
DOI:https://doi.org/10.2172/6064593· OSTI ID:6064593
Under this contract, the following goals were set. (1) Development and construction of an experimental system for the study of the kinetics of excimers, and demonstrate the validity of the low-pressure approach to such studies. The apparatus was to consist of the following: (a) cluster-molecular-beam source of van der Waals dimers and higher oligomers; (b) modulated-beam mass spectrometer; (c) low-energy electron beam for the production of excimers; (d) vacuum-ultraviolet to Visible detection and photon-counting system to monitor excimer emission; (e) flash-excited tunable laser for studies of resonant self-absorptions. (2) Form Ar/sub 2/ in its van der Waals ground state. (3) Produce Ar/sub 2/* by electron bombardment of Ar/sub 2/. (4) Perform fluorescence and photon absorption studies of Ar/sub 2/*. At the end of the contract period, goals 1 and 2 have been met; experiments 3 and 4 have been designed.
Research Organization:
Virginia Polytechnic Inst. and State Univ., Blacksburg (United States). Dept. of Chemistry
Sponsoring Organization:
USDOE
DOE Contract Number:
AS02-76DP40071
OSTI ID:
6064593
Report Number(s):
DOE/DP/40071--T1; COO--2810-11; ON: DE81028316
Country of Publication:
United States
Language:
English